Heavy oil upgrading currently the most common unit operation for heavy oil upgrading is a refinery process, the coker. To understand the delayed coking process, one must understand how the delayed coker is integrated with the rest of the refinery. There are three types of cokers used in oil refineries. Apr 14, 2016 see epas about pdf page to learn more. The coalbased jet fuel program ems energy institute. Delayed coking is one of the chemical engineering unit processes used in many petroleum refineries. In the next section figure 3 and figure 4, the temperaturepressure profile, will then be utilized to describe the basic process in an. Removing personnel from the cutting deck and operating the system remotely are the keys to greatly improved unit safety.
We overhauled the turbine in this opportunity and replaced the turbine rotor with spare rotor. The 33,000 barrelsperday bpd sulfuric acid alkylation unit had an unplanned shutdown from august 9 through august 12, 2017. Test report emission test program epa information collection. A delayed coker is a type of coker whose process consists of heating a residual oil feed to its thermal cracking temperature in a furnace with multiple parallel passes. The coking unit converts heavy feedstocks into solid coke and lower boiling hydrocarbon products which are suitable as feedstocks. Home forums coking maintenance pumps, valves, rotary joints, cranes pumps delayed coker pump seals this topic contains 3 replies, has 3 voices, and was last updated by claus graf 12 years, 6 months ago.
Contaminants na, ca, low saturates or high asphaltenes, crude compatibility, solvent deasphalt. A 4drum delayed coking unit in a petroleum refinery. Hazards of delayed coker unit dcu operations august 2003 once removed from the coke drums, the coke is transported away from the receiving area. The delayed coker unit is basically a tertiary unit for producing value added products such as petroleum cokepetcoke. Fines, or solids, in delayedcoker feedstocks reduce the ability of the coker to utilize capacity fully. Known as mother unit of the refinery, consist of crude distillation unit cdu.
The one that is by far the most commonly used is the delayed coker. Delayed coker upgrades low value residual fuel into higher value light products rum total coker unit liquid volume yield is approximately 80% of throughput. Pdf advanced control of the delayed coking unit in khartoum. Delayed coker simulation and tutorial simulation gses envision simulation is a realtime dynamic process simulation program used for operator training. Delayed coker unit for bottom upgradation 156 kbpd capacity processed 19 types of crudes api range. All equipment including the coke cutting systems have to meet these. Dcu delayed coker unit epa environmental protection agency ftir fourier transform infrared spectrometer h 2 s hydrogen sulfide ldl lower detection limit. July 28 through august 8, 2017, and from august 30 through august 31, 2017. The feed to sulphur recovery unit contains toxic h2s runway reaction at sru during dechocking operation vulnerability from process hazards. Hazards of delayed coker unit dcu operations august 2003 of dcu. Today we offer a full range of products for delayed coking including bottom and top coke drum unheading valves, isolation valves, hydraulic and electric actuation, controls and interlocks, autoswitch coke cutting tools and enclosures, and the retractable center feed injection device.
In one such study the source of chloride in coker distillation column was identified to be the desalter drain water containing soluble mg and ca chlorides which was added to the slop. Feed to coking unit is heavy hydrocarbon from bottom of different units and also includes slop. Complete overhauling of steam turbine done sucessfully. Hazards of delayed coker unit dcu operations august 2003. Chemical emergency preparedness and prevention office page 3. Impact there are always organic fines in the delayedcoker process. Valero had two unplanned shutdowns of the 16,000 bpd delayed coker unit from. The intent will be to identify and compare the various osbl requirements for each example. Hazards of delayed coker unit dcu operations epa nepis. Btl congress, berlin scroll down to pdf page 9 of 21 pdf pages.
In addition to the delayed coker, the complex will include a diesel hydrotreater, gas fractionation unit, sulfur and hydrogen production units, and associated systems. On april 26, the refinery shut down the delayed coker unit. Hazards of delayed coker unit dcu operations showing 14 of 8 pages in this text. Hydraulic load per module temperature of wastewater max peak oil at inlet total oil outlet predeoiler total oil outlet api separator ph at daf outlet sulphide at daf outlet total oil at daf outlet bod removal by. The major advantage is the relatively low investment cost versus the gain in value, in addition to the simplicity of the technology, and the combined emission control features.
May 09, 2020 a delayed coker drum operates at a temperature between 779 to 842 fahrenheit 415 to 450 celsius, where complex molecules break down into simpler ones, and some compounds act as free radicals to combine with others into olefins in the alkene chemical group. Limetree bay terminals assets fire fighting 3 fire trucks 5,000 gpm 1 gun platforms 8000 gpm rescue vehicle ambulance hazmat trailer 4 support vehicles 3 foam tankers 2 water tankers. The process thermally cracks the long chain hydrocarbon molecules in the residual oil feed into shorter chain molecules leaving behind the excess carbon in the form of. Delayed coker feed originates from the crude oil supplied to the refinery. You may need a pdf reader to view some of the files on this page. Review and survey of alkaline carbonate stress corrosion. The new additions will also enable the refinery to further increase utilisation of each barrel of omani crude. It is based upon a rigorous and highfidelity mathematical process model to provide a realistic dynamic response of a process unit.
Energy recovery at a delayed coker unit this example is a description of the steps required to carry out a pinch study of a refinery delayed coker unit. Our delayed coker unit fractionator boot water chloride. On april 25, the refinery was forced to shut down the diesel hydrotreater unit for unplanned repairs. Reproduced with permission from valero energy corporation. Residuum processing delayed coking delayed coking is a thermal process in which the vacuum residue from crude distillation is heated in a furnace then confined in a reaction zone or coke drum under proper operating conditions of temperature and pressure until the unvaporized portion of the furnace effluent is converted to vapor and coke. Residue upgradation options delayed coker unit, ranked second on margins, selected for residue upgradation. Sep 24, 2007 home forums coking maintenance pumps, valves, rotary joints, cranes pumps delayed coker pump seals this topic contains 3 replies, has 3 voices, and was last updated by claus graf 12 years, 6 months ago. Shell martinez refinery regulation 12 rule 15 air monitoring plan july 24, 2017 rev 1. Impact of feed properties and operating parameters on delayed. Biological sludge is thickened, stabilised, dewatered and disposed off to landfill. Reliable valve automation is critical to delayed coker. Dec 26, 2016 the delayed coker unit is basically a tertiary unit for producing value added products such as petroleum cokepetcoke. The delayed coking complex will be built at the 17 milliontonyear kstovo refinery in central russias nizhny novgorod region. The following specific operations and more general situations and conditions contribute most.
Work is fast and continuous, and downtime is crippling to production. A typical schematic flow diagram of a delayed coking unit. Tesoro refining and marketing company tesoro has permanently shutdown the fluid coking unit and its associated equipment and has replaced it with a delayed coking unit. Hazards of delayed coker unit dcu operations unt digital. From here, the coke is either exported from the refinery or crushed, washed, and stored prior to export. The schematic flow diagram below depicts a typical delayed coker. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke delayed coking is one of the unit processes used in many oil refineries. Delayed cokers can convert even the heaviest residues to lighter distillates provides much needed flexibility to the refiners to process a wide variety of crude oil and therefore, is the most widely used process all over the world. Jun 30, 2016 test report emission test program epa information collection request for delayed coking units 736 coker unit the testing was conducted on july 18 through august 3, 2011 on the 736 delayed coking unit dcu in response to the usepa section 114 information collection request icr for petroleum refineries. Delayed coking, the cornerstone of my subject, is one of, if not the most attractive option. Basics of refining and optimization valero energy corp. Many existing facilities are now installing new lowpressure refinery flaregas recovery systems. It was originally planned to run delayed coker unit fro 10 days and then shutdown it fro 12 days to make other units ready.
The main objective of the delayed the main objective of the delayed coking unit is to convert low value residual products to lighter products of higher value and to produce a coke product. Swri installed,commissioned and energy source by making. Another advantage is that delayed coking offers a potential. The delayed coker unit dcu and the fcc gascon dry gas is treated in an amine unit with mdea, in order to eliminate h2s, prior to injection into the refinery fuel gas system. Impact of feed properties and operating parameters on. What links here related changes upload file special pages permanent link page information. Once removed from the coke drums, the coke is transported away from the receiving area. A delayed coker is terminology used for a petroleum refining process that involves the further refining of residual oil byproducts after distillation of crude oil has taken place into useful fuels such as naptha and gasoline.
Table 41 1 736 coker unit particulate matter test results summary 416 table 41 2 736 coker unit metals test results summary 417 table 41 3 736 coker unit trs test results summary 419 table 41 4 736 coker unit cos, cs2 and h2s test results summary 420 table 41 5 736 coker unit so2, no, co, thc, ch4 and c2h6, test results 421. In its simplest terms, delayed coking is a semibatch thermal cracking process using alternating drums that are switched offline after filling. Tesoro has submitted this application to in order to bank emission reduction credits ercs from the reduction in emissions from converting the fluid coker to a delayed coker. This is one of the major advantages of the delayed coking process. Next goal is further scaleup to pilotplant operation. The objective of this presentation is to illustrate in concrete terms the different steps in a pinch analysis of an industrial process in a retrofit situation. Support facilities include closed blowdown, coke cutting and handling, and a water recovery system. Test report emission test program epa information collection request for delayed coking units 736 coker unit the testing was conducted on july 18 through august 3, 2011 on the 736 delayed coking unit dcu in response to the usepa section 114 information collection request icr for petroleum refineries. Delayed coking operational optimization refining community. Despite the advent of fracking technologies and the production of lighter. Hazards of delayed coker unit dcu operations august 2003 pdf 8 pp, 377 k. The process was first patented in 1891 by a russian engineer named vladimir shukhov, and the shukhov cracking process is still used into 2011 to produce diesel fuel.
Analysena, mg and ca chloride in vacuum residue water 4. We can make longduration runs which simulate delayed coker operations, and produce quantities of liquid and solid products for further testing. A coker or coker unit is an oil refinery processing unit that converts the residual oil from the vacuum distillation column into low molecular weight hydrocarbon gases, naphtha, light and heavy gas oils, and petroleum coke. A coker operates on the principle of thermal crack. This cracks the heavy, long chain hydrocarbon molecules of the residual oil into coker gas oil and petroleum coke.
A refinerys delayed coking unit is not new technology, but is the most common process to upgrade the residual hydrocarbons remaining after upstream. However, operational problems have been experienced at the amine unit, due to mdea degradation and the presence of heat stable salts hss, among other factors. Engineering evaluation tesoro refining and marketing. This design modification significantly reduces routine emissions to the refinery flare system from the delayed coker unit. Flowserve corporation 5215 north oconnor boulevard suite 2300 irving, texas 75039 north america latin america europe. Therefore, brief descriptions of each of the processing steps preceding the delayed coking unit are provided below. Pdf delayed coking units convert heavy crude oil or topping refinery residue to more light valuable products including diesel, gasoline and naphtha by. The refinery expected to complete repairs and accelerated maintenance on the coker unit by may 15. Coking is a refinery unit operation that upgrades material called bottoms from the atmospheric or vacuum distillation column into highervalue products and, as the name implies, produces petroleum coke a coallike material. Eil is jointly licensing the delayed coker technology by. Delayed coker units dcus in india are built in extreme ambient.
The simplified data used to illustrate the procedure is based on an amalgamation of four different existing delayed coker units. Hazards of delayed coker unit dcu operations august 2003 pdf 8 pp, 377 k contact us to ask a question, provide feedback, or report a problem. The cracking occurred in the piping between the second stage separator and downstream fractionator. Continually developing new burner technology for lower nox and optimal flame pattern better online spalling procedures. Delayed coking operational optimization use of 6pass double fired coker heaters for larger coke drum module capacities and 3pass double fired coker heaters for smaller drum module capacities.